#45 Bulgaria
Bulgaria is one of the few unexplored countries of Europe, which offers stunning beaches, historic cathedrals, a variety of winter sports activities, fantastic trekking, and historic towns open to everybody but not overrun with tourists. In general, Bulgaria is very safe. Car theft and break-ins are the most common types of crime, while overall crime rates are low. The red-light district near the Pliska Hotel and the parks close to Lion's Bridge (Lvov Most) are places to avoid or exercise extra precautions at.
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#46 Albania
Albania is one of those places where you never know what to expect. Located a little off the beaten path, it's full of surprises, which makes for a unique experience. It's generally safe to go to Albania. Mild dangers exist, but nothing that should prevent you from going there. The only location you should avoid is Albania's border with Kosovo.